Synthesis and crystal structure of chloro{bis[N,N'-(2-chlorobenzylidene)]ethylenediamine}(triphenylphosphine)copper(I) - ePrints

Synthesis and crystal structure of chloro{bis[N,N'-(2-chlorobenzylidene)]ethylenediamine}(triphenylphosphine)copper(I)

Lookup NU author(s): Professor Mohammad Habibi,Dr Ross Harrington,Emeritus Professor Bill CleggORCiD

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Abstract

The crystal structure of CuL(PPh3)Cl (L = bis(N,N'-2-chlorobenzylidene)ethylenediamine) was detd. by an x-ray diffraction method. The title Cu(I) complex crystallizes in the monoclinic space group P21/n with a 10.2203(9), b 21.545(6), c 14.060(3).ANG., beta = 101.854(10) and Z = 4. The structure was refined to the final R1 = 0.0320 using all 6931 obsd. reflections. The coordination polyhedron around the CuI center in this complex is best described as a distorted tetrahedron. [on SciFinder (R)]

Publication metadata

Author(s): Habibi MH, Montazerozohori M, Barati K, Harrington RW, Clegg W

Publication type: Article

Publication status: Published

Journal: Analytical Sciences. X-ray Structure Analysis Online

Year: 2007

Volume: 23

Issue: 3

Pages: x45-x46

ISSN (print): 1348-2238

Publisher: Nihon Bunseki Kagakkai

URL:

DOI: 10.2116/analscix.23.x45

Notes: CAN 149:23391 78-7 Inorganic Chemicals and Reactions Department of Chemistry,University of Isfahan,Esfahan,Iran. Journal; Online Computer File 1348-2238 written in English. 81512-53-0P Role: PRP (Properties), SPN (Synthetic preparation), PREP (Preparation) (for prepn. of copper bis(chlorobenzylidene)ethylenediamine phosphine chloro complex); 1029997-25-8P Role: PRP (Properties), SPN (Synthetic preparation), PREP (Preparation) (prepn. and crystal structure of)

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